Staff directory Jiemin Wang

Publications

2021

  • Spontaneous phase segregation of Sr2NiO3 and SrNi2O3 during SrNiO3 heteroepitaxy

    Wang L., Yang Z., Yin X., Taylor S.D., He X., Tang C.S., Bowden M.E., Zhao J., Wang J., Liu J., Perea D.E., Wangoh L., Wee A.T.S., Zhou H., Chambers S.A., Du Y. Science Advances; 7 (10, eabe2866) 2021. 10.1126/sciadv.abe2866. IF: 13.117

    Recent discovery of superconductivity in Nd0.8Sr0.2NiO2 motivates the synthesis of other nickelates for providing insights into the origin of high-temperature superconductivity. However, the synthesis of stoichiometric R1−xSrxNiO3 thin films over a range of x has proven challenging. Moreover, little is known about the structures and properties of the end member SrNiO3. Here, we show that spontaneous phase segregation occurs while depositing SrNiO3 thin films on perovskite oxide substrates by molecular beam epitaxy. Two coexisting oxygen-deficient Ruddlesden-Popper phases, Sr2NiO3 and SrNi2O3, are formed to balance the stoichiometry and stabilize the energetically preferred Ni2+ cation. Our study sheds light on an unusual oxide thin-film nucleation process driven by the instability in perovskite structured SrNiO3 and the tendency of transition metal cations to form their most stable valence (i.e., Ni2+ in this case). The resulting metastable reduced Ruddlesden-Popper structures offer a testbed for further studying emerging phenomena in nickel-based oxides. Copyright © 2021 The Authors, some rights reserved;


2020

  • Size-Dependent Pulmonary Impact of Thin Graphene Oxide Sheets in Mice: Toward Safe-by-Design

    Rodrigues A.F., Newman L., Jasim D., Mukherjee S.P., Wang J., Vacchi I.A., Ménard-Moyon C., Bianco A., Fadeel B., Kostarelos K., Bussy C. Advanced Science; 7 (12, 1903200) 2020. 10.1002/advs.201903200. IF: 15.840

    Safety assessment of graphene-based materials (GBMs) including graphene oxide (GO) is essential for their safe use across many sectors of society. In particular, the link between specific material properties and biological effects needs to be further elucidated. Here, the effects of lateral dimensions of GO sheets in acute and chronic pulmonary responses after single intranasal instillation in mice are compared. Micrometer-sized GO induces stronger pulmonary inflammation than nanometer-sized GO, despite reduced translocation to the lungs. Genome-wide RNA sequencing also reveals distinct size-dependent effects of GO, in agreement with the histopathological results. Although large GO, but not the smallest GO, triggers the formation of granulomas that persists for up to 90 days, no pulmonary fibrosis is observed. These latter results can be partly explained by Raman imaging, which evidences the progressive biotransformation of GO into less graphitic structures. The findings demonstrate that lateral dimensions play a fundamental role in the pulmonary response to GO, and suggest that airborne exposure to micrometer-sized GO should be avoided in the production plant or applications, where aerosolized dispersions are likely to occur. These results are important toward the implementation of a safer-by-design approach for GBM products and applications, for the benefit of workers and end-users. © 2020 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim


  • Synergistic computational-experimental discovery of highly selective ptcu nanocluster catalysts for acetylene semihydrogenation

    Ayodele O.B., Cai R., Wang J., Ziouani Y., Liang Z., Spadaro M.C., Kovnir K., Arbiol J., Akola J., Palmer R.E., Kolen'ko Y.V. ACS Catalysis; 10 (1): 451 - 457. 2020. 10.1021/acscatal.9b03539. IF: 12.350

    Semihydrogenation of acetylene (SHA) in an ethylene-rich stream is an important process for polymer industries. Presently, Pd-based catalysts have demonstrated good acetylene conversion (XC2H2), however, at the expense of ethylene selectivity (SC2H4). In this study, we have employed a systematic approach using density functional theory (DFT) to identify the best catalyst in a Cu-Pt system. The DFT results showed that with a 55 atom system at∼1.1 Pt/Cu ratio for Pt28Cu27/Al2O3, the d-band center shifted -2.2 eV relative to the Fermi level leading to electron-saturated Pt, which allows only adsorption of ethylene via a π -bond, resulting in theoretical 99.7% SC2H4 at nearly complete XC2H2. Based on the DFT results, Pt-Cu/Al2O3 (PtCu) and Pt/Al2O3 (Pt) nanocatalysts were synthesized via cluster beam deposition (CBD), and their properties and activities were correlated with the computational predictions. For bimetallic PtCu, the electron microscopy results show the formation of alloys. The bimetallic PtCu catalyst closely mimics the DFT predictions in terms of both electronic structure, as confirmed by X-ray photoelectron spectroscopy, and catalytic activity. The alloying of Pt with Cu was responsible for the high C2H4 specific yield resulting from electron transfer between Cu and Pt, thus making PtCu a promising catalyst for SHA. © 2019 American Chemical Society.