Staff directory David Pesquera Herrero

David Pesquera Herrero

Postdoctoral Researcher
Oxide Nanophysics



  • Correlating Surface Crystal Orientation and Gas Kinetics in Perovskite Oxide Electrodes

    Gao R., Fernandez A., Chakraborty T., Luo A., Pesquera D., Das S., Velarde G., Thoréton V., Kilner J., Ishihara T., Nemšák S., Crumlin E.J., Ertekin E., Martin L.W. Advanced Materials; 2021. 10.1002/adma.202100977. IF: 27.398

    Solid–gas interactions at electrode surfaces determine the efficiency of solid-oxide fuel cells and electrolyzers. Here, the correlation between surface–gas kinetics and the crystal orientation of perovskite electrodes is studied in the model system La0.8Sr0.2Co0.2Fe0.8O3. The gas-exchange kinetics are characterized by synthesizing epitaxial half-cell geometries where three single-variant surfaces are produced [i.e., La0.8Sr0.2Co0.2Fe0.8O3/La0.9Sr0.1Ga0.95Mg0.05O3−δ/SrRuO3/SrTiO3 (001), (110), and (111)]. Electrochemical impedance spectroscopy and electrical conductivity relaxation measurements reveal a strong surface-orientation dependency of the gas-exchange kinetics, wherein (111)-oriented surfaces exhibit an activity >3-times higher as compared to (001)-oriented surfaces. Oxygen partial pressure ((Formula presented.))-dependent electrochemical impedance spectroscopy studies reveal that while the three surfaces have different gas-exchange kinetics, the reaction mechanisms and rate-limiting steps are the same (i.e., charge-transfer to the diatomic oxygen species). First-principles calculations suggest that the formation energy of vacancies and adsorption at the various surfaces is different and influenced by the surface polarity. Finally, synchrotron-based, ambient-pressure X-ray spectroscopies reveal distinct electronic changes and surface chemistry among the different surface orientations. Taken together, thin-film epitaxy provides an efficient approach to control and understand the electrode reactivity ultimately demonstrating that the (111)-surface exhibits a high density of active surface sites which leads to higher activity. © 2021 Wiley-VCH GmbH

  • Pyroelectric thin films - Past, present, and future

    Velarde G., Pandya S., Karthik J., Pesquera D., Martin L.W. APL Materials; 9 (1, 010702) 2021. 10.1063/5.0035735. IF: 3.819

    Pyroelectrics are a material class that undergoes a change in polarization as the temperature of the system is varied. This effect can be utilized for applications ranging from thermal imaging and sensing to waste-heat energy conversion to thermally driven electron emission. Here, we review recent advances in the study and utilization of thin-film pyroelectrics. Leveraging advances in modeling, synthesis, and characterization has provided a pathway forward in one of the more poorly developed subfields of ferroelectricity. We introduce the complex physical phenomena of pyroelectricity, briefly explore the history of work in this space, and highlight not only new advances in the direct measurement of such effects but also how our ability to control thin-film materials is changing our understanding of this response. Finally, we discuss recent advances in thin-film pyroelectric devices and introduce a number of potentially new directions the field may follow in the coming years. © 2021 Author(s).


  • Beyond Expectation: Advanced Materials Design, Synthesis, and Processing to Enable Novel Ferroelectric Properties and Applications

    Kim J., Lupi E., Pesquera D., Acharya M., Zhao W., Velarde G.A.P., Griffin S., Martin L.W. MRS Advances; 2020. 10.1557/adv.2020.344. IF: 0.000

    Ferroelectrics and related materials (e.g., non-traditional ferroelectrics such as relaxors) have long been used in a range of applications, but with the advent of new ways of modeling, synthesizing, and characterizing these materials, continued access to astonishing breakthroughs in our fundamental understanding come each year. While we still rely on these materials in a range of applications, we continue to re-write what is possible to be done with them. In turn, assumptions that have underpinned the use and design of certain materials are progressively being revisited. This perspective aims to provide an overview of the field of ferroelectric/relaxor/polar-oxide thin films in recent years, with an emphasis on emergent structure and function enabled by advanced synthesis, processing, and computational modeling. Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press.

  • Beyond Substrates: Strain Engineering of Ferroelectric Membranes

    Pesquera D., Parsonnet E., Qualls A., Xu R., Gubser A.J., Kim J., Jiang Y., Velarde G., Huang Y.-L., Hwang H.Y., Ramesh R., Martin L.W. Advanced Materials; 32 (43, 2003780) 2020. 10.1002/adma.202003780. IF: 27.398

    Strain engineering in perovskite oxides provides for dramatic control over material structure, phase, and properties, but is restricted by the discrete strain states produced by available high-quality substrates. Here, using the ferroelectric BaTiO3, production of precisely strain-engineered, substrate-released nanoscale membranes is demonstrated via an epitaxial lift-off process that allows the high crystalline quality of films grown on substrates to be replicated. In turn, fine structural tuning is achieved using interlayer stress in symmetric trilayer oxide-metal/ferroelectric/oxide-metal structures fabricated from the released membranes. In devices integrated on silicon, the interlayer stress provides deterministic control of ordering temperature (from 75 to 425 °C) and releasing the substrate clamping is shown to dramatically impact ferroelectric switching and domain dynamics (including reducing coercive fields to <10 kV cm−1 and improving switching times to <5 ns for a 20 µm diameter capacitor in a 100-nm-thick film). In devices integrated on flexible polymers, enhanced room-temperature dielectric permittivity with large mechanical tunability (a 90% change upon ±0.1% strain application) is demonstrated. This approach paves the way toward the fabrication of ultrafast CMOS-compatible ferroelectric memories and ultrasensitive flexible nanosensor devices, and it may also be leveraged for the stabilization of novel phases and functionalities not achievable via direct epitaxial growth. © 2020 Wiley-VCH GmbH